Ruthenium‐Assisted Tellurium Abstraction in Bis(thiophen‐2‐yl) Ditelluride

نویسندگان

چکیده

The reaction of [RuCl2(CO)3]2 and Te2Tpn2 (Tpn=thiophen-2-yl, C4H3S) in the absence light resulted formation cct-[RuCl2(CO)2(TeTpn2)2] (1) [cis(Cl)-cis(CO)-trans(TeTpn2)] TeTpn2 (2) together with precipitation tellurium. complex 1 monotelluride 2 were characterized by NMR spectroscopy single-crystal X-ray diffraction. decomposition to has been monitored 125Te seemed be faster than ligand substitution TeTpn2. A catalytic cycle is proposed for based on PBE0-D3/def2-TZVP calculations.

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ژورنال

عنوان ژورنال: European Journal of Inorganic Chemistry

سال: 2023

ISSN: ['1434-1948', '1099-0682']

DOI: https://doi.org/10.1002/ejic.202200772